[5-(Pyridin-2-yl)-1H-tetrazole-κ2 N 4,N 5]bis(triphenylphosphane-κP)copper(I) tetrafluoridoborate
نویسندگان
چکیده
In the title Cu(I) compound, [Cu(C6H5N5)(C18H15P)2]BF4, the Cu(I) cation is N,N'-chelated by a 5-(pyridin-2-yl)-1H-tetra-zole ligand and coordinated by two triphenyl-phosphane ligands in a distorted tetra-hedral geometry. The tetra-zole and pyridine rings are essentially coplanar [dihedral angle = 4.1 (3)°]. The tetra-fluoridoborate anion links to the complex cation via an N-H⋯F hydrogen bond.
منابع مشابه
catena-Poly[[(triphenylphosphane-κP)copper(I)]-di-μ-bromido-[(triphenylphosphane-κP)copper(I)]-μ-1,3-bis(pyridin-4-yl)propane-κ2 N:N′]
Through a diffusion reaction, cuprous bromide, triphenyl-phosphane and 1,3-bis-(pyridin-4-yl)propane (bpp) were self-assembled to form the one-dimensional title compound, [Cu(2)Br(2)(C(13)H(14)N(2))(C(18)H(15)P)(2)](n). Each Cu(I) atom is coordinated by two Br atoms, one P atom from a triphenyl-phosphane ligand and one N atom from a bpp mol-ecule in a distorted tetra-hedral geometry. Two μ(2)-B...
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The title compound, [Pd(C(6)H(4)N(2)S(2))(C(18)H(15)P)(2)], was obtained as a minor product from the reaction of trans-PdCl(2)(PPh(3))(2) with piperazine-1,4-dicarbothioic acid bis-(pyridin-2-yl)amide. The Pd(II) atom displays a slightly distorted square-planar PdP(2)S(2) geometry with a bidentately coordinated pyridin-2-ylcarbonimidodithio-ate ligand and two triphenyl-phosphine mol-ecules, coo...
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In the title coordination polymer, [Cu(2)I(2)(C(14)H(14)N(4))(C(18)H(15)P)(2)](n), the Cu(I) atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra-hedral arrangement. A crystallographic inversion centre generates a Cu(2)I(2) diamond with a Cu-Cu separation of 3.0120 (5) Å. The complete N,N'-(1-pyridin-4-yl-ethethyl-idene)-hydrazine mol-ecule is also generated b...
متن کامل[6-(4-Bromophenyl)-2,2′-bipyridine-κ2 N,N′](tricyclohexylphosphine-κP)copper(I) tetrafluoridoborate
In the title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(33)P)]BF(4), the Cu(I) atom is three-coordinated in a distorted trigonal configuration by two N atoms from the 6-(4-bromo-phen-yl)-2,2'-bipyridine ligand and a P atom from the tricyclo-hexyl-phosphine ligand. In addition, a weak anion⋯Cu(I) inter-action with a nearest F⋯Cu separation of 2.696 (5) Å is found.
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